Electrochemical or Galvanic or Voltaic Cells

Electrochemical or Galvanic or Voltaic Cells

An Electrochemical Cell is a device used to convert chemical energy (produced in a redox reaction) into electrical energy.

Electrochemical Cells are also known as Galvanic or Voltaic Cells.

If we take a zinc rod and place it in a container filled with copper sulphate solution heat will be produced. This happens due a spontaneous redox reaction given below:

Zn(Solid) + CuSO4(Aqueous) ZnSO4(Aqueous) + Cu (Solid) deposited

As the reaction would proceed the zinc rod would get eroded ,copper particles would get deposited and solution would becom warm


It would be useful to be able to convert this chemical energy to electrical energy instead of heat energy. This is done by an electrochemical cell.

Construction of an Electrochemical Cell

Let us use the redox reaction given below to explain the construction of an Electrochemical Cell.

Zn(Solid) + CuSO4(Aqueous) ZnSO4(Aqueous) + Cu (Solid)

The ionic form of the reaction is:

Zn + Cu2+ Zn2+ + Cu

This reaction can be split into the following two half reactions.

1. Oxidation half reaction

Zn Zn2+ + 2e

2. Reduction half reaction

Cu2+ + 2e Cu

An Electrochemical Cell

The oxidation reaction in the zinc rod releases two electrons.These two electrons are taken by the Copper ion in the copper sulphate solution.

If these two half reactions can be separated then the electrons can be made to move through a wire.

In this manner we can produce electical energy from chemical energy.

The salt bridge is a concentrated solution of inert electrolytes. It is required for completing the circuit. It allows the movement of ions from one solution to the other.